a, PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(FeO+2HCl\rightarrow FeCl_2+H_2O\)

b, Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,2\left(mol\right)\)

\(\Rightarrow m_{Al}=0,2.27=5,4\left(g\right)\)

⇒ m_FeO = 12,6 - 5,4 = 7,2 (g)

c, Phần này đề cho dd NaOH dư hay vừa đủ bạn nhỉ?

d, Cho hh vào dd H₂SO₄ đặc nguội thì có khí thoát ra.

PT: \(2FeO+4H_2SO_{4\left(đ\right)}\rightarrow Fe_2\left(SO_4\right)_3+SO_2+4H_2O\)

Ta có: \(n_{FeO}=\dfrac{7,2}{72}=0,1\left(mol\right)\)

Theo PT: \(n_{SO_2}=\dfrac{1}{2}n_{FeO}=0,05\left(mol\right)\)

\(\Rightarrow V_{SO_2}=0,05.22,4=1,12\left(l\right)\)

\(a,2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ b,n_{H_2}=\dfrac{6,72}{22,4}=0,3(mol)\\ \Rightarrow n_{Al}=0,2(mol)\\ \Rightarrow m_{Al}=0,2.27=5,4(g)\\ c,n_{H_2SO_4}=0,3(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,3.98}{9,8\%}=300(g)\\ d,n_{Al_2(SO_4)_3}=0,1(mol)\\ \Rightarrow C\%_{Al_2(SO_4)_3}=\dfrac{0,1.342}{5,4+300-0,3.2}.100\%=11,22\%\)

\(n_{Al}=\dfrac{5.4}{27}=0.2\left(mol\right)\)

\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

\(0.2..........0.3...............0.1...........0.3\)

\(m_{H_2SO_4}=0.3\cdot98=29.4\left(g\right)\)

\(V_{H_2}=0.3\cdot22.4=6.72\left(l\right)\)

\(m_{dd_{H_2SO_4}}=\dfrac{29.4\cdot100}{20}=147\left(g\right)\)

\(m_{Al_2\left(SO_4\right)_3}=0.1\cdot342=34.2\left(g\right)\)

\(m_{\text{dung dịch sau phản ứng }}=5.4+147-0.3\cdot2=151.8\left(g\right)\)

\(C\%_{Al_2\left(SO_4\right)_3}=\dfrac{34.2}{151.8}\cdot100\%=22.53\%\)

PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)

a) Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)=n_{Fe}\)

\(\Rightarrow m_{Fe}=0,25\cdot56=14\left(g\right)\) \(\Rightarrow m_{Cu}=6\left(g\right)\)

b) Theo PTHH: \(n_{FeSO_4}=0,25mol\) \(\Rightarrow m_{FeSO_4}=0,25\cdot152=38\left(g\right)\)

Mặt khác: \(\left\{{}\begin{matrix}m_{ddH_2SO_4}=\dfrac{0,25\cdot98}{10\%}=245\left(g\right)\\m_{H_2}=0,25\cdot2=0,5\left(g\right)\end{matrix}\right.\)

\(\Rightarrow m_{dd}=m_{hh}+m_{H_2SO_4}-m_{Cu}-m_{H_2}=258,5\left(g\right)\)

\(\Rightarrow C\%_{FeSO_4}=\dfrac{38}{258,5}\cdot100\%\approx14,7\%\)

pthh : Fe +H₂SO₄ → FeSO₄ +H₂

theo bài ra số mol của h2 =0,15 (mol)

theo pt : nFe=nH₂=0,15 (mol)

mFe=0,15 .56 =8,4 (g) ⇒mCu=20-8,4=11,6 (g)

\(n_{CO2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Pt : \(MCO_3+H_2SO_4\rightarrow MgSO_4+CO_2+H_2O|\)

           1              1                 1            1         1

          0,1           0,1                            0,1       0,1

\(n_{MCO3}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)

Có : \(0,1.\left(M=60\right)=8,4\)

               \(\left(M+60\right)=84\)

              \(M=84-60=24\left(dvc\right)\)

          Vậy kim loại M là magie

\(n_{H2SO4}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)

⇒ \(m_{H2SO4}=0,1.98=9,8\left(g\right)\)

\(m_{ddH2SO4}=\dfrac{9,8.100}{12,25}=80\left(g\right)\)

\(n_{MgSO4}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)

⇒ \(m_{MgSO4}=0,1.120=12\left(g\right)\)

\(m_{ddspu}=8,4+80=88,4\left(g\right)\)

\(C_{MgSO4}=\dfrac{12.100}{88,4}=13,57\)⁰/₀

 Chúc bạn học tốt

a) \(n_{SO_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

\(n_{NaOH}=0,5.2=1\left(mol\right)\)

PTHH: 2NaOH + SO₂ --> Na₂SO₃ + H₂O

               1------->0,5------>0,5

             Na₂SO₃ + SO₂ + H₂O --> 2NaHSO₃

                0,1<-----0,1--------------->0,2

=> Thu được muối Na₂SO₃, NaHSO₃

\(\left\{{}\begin{matrix}m_{Na_2SO_3}=0,4.126=50,4\left(g\right)\\n_{NaHSO_3}=0,2.104=20,8\left(g\right)\end{matrix}\right.\)

b) \(\left\{{}\begin{matrix}C_{M\left(Na_2SO_3\right)}=\dfrac{0,4}{0,5}=0,8M\\C_{M\left(NaHSO_3\right)}=\dfrac{0,2}{0,5}=0,4M\end{matrix}\right.\)